A Metal-Organic Framework with a Covalently Prefabricated Porous Organic Linker

作者:Swamy Shashikala I; Bacsa John; Jones James T A; Stylianou Kyriakos C; Steiner Alexander; Ritchie Lyndsey K; Hasell Tom; Gould Jamie A; Laybourn Andrea; Khimyak Yaroslav Z; Adams Dave J; Rosseinsky Matthew J*; Cooper Andrew I
来源:Journal of the American Chemical Society, 2010, 132(37): 12773-12775.
DOI:10.1021/ja104083y

摘要

We report here the synthesis of a metal organic framework comprising an organic cage linker with covalently prefabricated, intrinsic porosity. The network can be compared to a porous rock salt structure where the pores are partially filled by charge-balancing cations.

  • 出版日期2010-9-22