Hydrothermal synthesis and crystal structure of a Cadmium(II) polymer with one-dimensional chain structure: [Cd(MDPPz)(BDQ(H2O)](n)

作者：Li Chuan Bi^*; Zhou Shi; Li Xiu Mei; Liu Bo

来源：Chinese Journal of Structural Chemistry, 2007, 26(11): 1349-1352.

• cadmium compound
• crystal structure
• fluorescence

A metal-organic coordination compound formulated as [Cd(MDPPz)(BDC)(H2O)](n) 1 (MDPPz = 11-methyldipyrido[3,2-a:2',3'-c]phenazine, BDC = 1,4-benzenedicarboxylate) has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, fluorescence spectrum and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group C2/c, with a = 30.673(8), b = 9.623(3), c = 20.784(6) angstrom, beta = 98.646(3)degrees, V= 6065(3) angstrom(3), C27H17CdN4O5, M-r= 589.85, D-c = 1.292 g/cm(3), mu(MoK alpha) = 0.757 mm(-1), F(000) = 2360, Z = 8, the final R = 0.0381 and wR = 0.0855 for 4191 observed reflections (I > 2 sigma(I)). 1 exhibits blue fluorescence property at room temperature.

• 出版日期2007
• 单位吉林师范大学; 通化师范学院