Dehydrochlorination of chloroform by N-methyl-N,N-bis(silatranylmethyl)amine

作者：Lazareva N F^*; Lazarev I M

来源：Russian Chemical Bulletin, 2011, 60(3): 598-600.

DOI：10.1007/s11172-011-0095-x

• N-methyl-N,N-bis(silatranylmethyl)amine
• chloroform
• dichlorocarbene
• dehydrochlorination

N,N-Bis(silatranylmethyl)methylamine 1 reacts with chloroform resulting in amine hydrochloride 2 and dichlorocarbene. The formation of the latter was proved by a cyclopropanation reaction and insertion into the Si-H bond. In the presence of cyclohexene, compound 2 and 7,7-dichlorobicyclo[4.1.0]heptane are the major reaction products. Compound 2 and 1-dichloromethylsilatrane were isolated upon the reaction of amine 1 with chloroform and 1-hydrosilantrane.

• 出版日期2011-3