Main-chain poly(ionic liquid)-derived nitrogen-doped microfrnesoporous carbons for CO2 capture and selective aerobic oxidation of alcohols

作者：Gong, Jiang; Lin, Huijuan; Grygiel, Konrad; Yuan, Jiayin^*

来源：Applied Materials Today, 2017, 7: 159-168.

DOI：10.1016/j.apmt.2017.02.009

• Nitrogen-doped porous carbon
• CO2 capture
• Selective aerobic oxidation
• Metal-free carbocatalyst
• Poly(ionic liquid)s

Sustainable development and the recent fast-growing global demands for energy and functional chemicals urgently call for effective methods for CO2 remediation and efficient metal-free catalysts for selective oxidation of aromatic alcohol. Herein, a unique main-chain poly(ionic liquid) (PIL) is employed as the precursor to prepare nitrogen-doped micro/mesoporous carbons via simultaneous carbonization and activation, which bear high yield, large specific surface area above 1700 m(2) g(-1) and rich nitrogen dopant. The porous carbon products deliver a high CO2 adsorption capacity up to 6.2 mmol g(-1) at 273 K and 1 bar with outstanding reversibility and satisfactory selectivity. Besides, they work excellently as metal-free carbocatalysts for the selective aerobic oxidation of benzyl alcohol to benzaldehyde with high selectivity. It is believed that this work not only provides a facile approach to prepare nitrogen-doped porous carbon, but also advances the related research in the fields of environment and catalysis.

• 出版日期2017-6