A water-soluble iridium(III) porphyrin

作者：Kanemitsu Hironobu; Harada Ryosuke; Ogo Seiji^*

来源：Chemical Communications, 2010, 46(18): 3083-3085.

DOI：10.1039/c000263a

This work reports the synthesis and characterization of the first water-soluble iridium porphyrin, iridium(III) diaqua porphyrin [Ir(III)(TSPP)(OH(2))(2)](3-) (1, TSPP = tetra-p-sulfonatophenyl porphyrin). The structure of 1 was unequivocally determined by single crystal X-ray analysis. Benzo-18-crown-6-ether is essential for producing single crystals suitable for X-ray analysis.

• 出版日期2010