Alkylation of p-cresol with camphene in the presence of aluminum-containing catalysts

作者：Chukicheva I Yu^*; Fedorova I V; Shumova O A; Kutchin A V

来源：Russian Journal of Bioorganic Chemistry, 2011, 37(7): 855-857.

DOI：10.1134/S106816201107003X

• alkylation
• camphene
• cresol
• terpenophenols

Alkylation of p-cresol with camphene was studied in the presence of aluminum-based catalysts (i-PrO)(3)Al, AlH(3), AlCl(3), (i-Bu)(2)AlH, EtAlCl(2), and LiAlH(4). Aluminum isopropylate was a selective catalyst for the preparation of ortho-isobornylphenol, its activity being close to that of aluminum phenolate.

• 出版日期2011-12