Toluene abatement through adsorption and plasma oxidation using ZSM-5 mixed with γ-Al2O3, TiO2 or BaTiO3

作者：Qin, Caihong^*; Guo, Hui; Liu, Pin; Bai, Wenwen; Huang, Jiayu; Huang, Xuemin; Dang, Xiaoqing^*; Yan, Dongjie

来源：Journal of Industrial and Engineering Chemistry, 2018, 63: 449-455.

DOI：10.1016/j.jiec.2018.03.005

• Toluene
• Adsorption-plasma oxidation
• Adsorbent/catalyst

Toluene abatement through adsorption and then plasma oxidation using ZSM-5, ZSM-5-gamma-Al2O3 (Z-Al), ZSM-5-TiO2 (Z-Ti), ZSM-5-BaTiO3 (Z-Ba), and AgMn/ZSM-5-BaTiO3 (AgMn/Z-Ba) as adsorbents/catalysts was investigated. The efficiency of toluene removal reached similar to 100% for all the tested adsorbents/catalysts. ZSM-5 had the lowest mineralization rate (MR) of similar to 43%, while Z-Ba had the highest MR (88%) with an S-CO2 of similar to 80%. After loading AgMn onto Z-Ba, both the breakthrough capacity of toluene and S-CO2 was increased, while the production of byproduct O-3 and MR was decreased. The mixed materials created a higher amount of active species capable of deeply oxidizing adsorbed toluene.

• 出版日期2018-7-25
• 单位中国环境科学研究院; 西安建筑科技大学