A donor-functionalized, silyl-substituted pentadienyllithium: structural insight from experiment and theory

作者：Solomon Sophia A; Bickelhaupt F Matthias^*; Layfield Richard A; Nilsson Mathias; Poater Jordi; Sola Miquel

来源：Chemical communications, 2011, 47(21): 6162-6164.

DOI：10.1039/c1cc11697e

A donor-functionalized, silyl-substituted pentadienyllithium has been synthesized and characterized by crystallography and NMR spectroscopy. The pentadienyl negative charge was found to be partially localized, which DFT revealed to be due to the polarizing power of the lithium cation.

• 出版日期2011