A novel parallel interpenetrating two-dimensional (4,4) network: poly[[mu(2)-1,4-bis(imidazol-1-ylmethyl)benzene](mu(2)-naphthalene-1,4-d icarboxylato) zinc(II)]

作者：Li Ya Ping; Sun Da Jun^*; Zang Hu; Su Guan Fang; Li Yu Lin

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2009, 65(9): M340-M342.

DOI：10.1107/S0108270109029084

In the title coordination compound, [Zn(C12H6O4)(C14H14N4)] n, the two Zn-II centers exhibit different coordination environments. One Zn-II center is four-coordinated in a distorted tetrahedral environment surrounded by two carboxylate O atoms from two different naphthalene-1,4-dicarboxylate (1,4-ndc) anions and two N atoms from two distinct 1,4-bis(imidazol-1-ylmethyl) benzene (1,4-bix) ligands. The coordination of the second Zn-II center comprises two N atoms from two different 1,4-bix ligands and three carboxylate O atoms from two different 1,4-ndc ligands in a highly distorted square-pyramidal environment. The 1,4-bix ligand and the 1,4-ndc anion link adjacent Zn-II centers into a two-dimensional four-connected (4,4) network. The two (4,4) networks are interpenetrated in a parallel mode.

• 出版日期2009-9
• 单位吉林大学