Spacer type mediated tunable spin crossover (SCO) characteristics of pyrene decorated 2,6-bis(pyrazol-1-yl)pyridine (bpp) based Fe(II) molecular spintronic modules

作者：Kumar Kuppusamy Senthil; Salitros Ivan; Moreno Pineda Eufemio; Ruben Mario

来源：Dalton Transactions, 2017, 46(30): 9765-9768.

DOI：10.1039/c7dt02219k

Two isomer-like, pyrene-decorated Fe(ii) spin crossover (SCO) complexes, <bold>[Fe(L1)2](BF4)2</bold> and <bold>[Fe(L2)2](BF4)2</bold>, exhibit a dramatic 140 K (ΔT1/2) variation in their switching temperatures.

• 出版日期2017-8-14
• 单位Karlsruhe Institute of Technology(KIT); Karlsruhe Institute of Technology (KIT); Université de Strasbourg