A highly-thermostable 3D Cd-II coordination framework based on a new 1,2,4-triazole derivatives: crystal structure, topology and luminescence

作者：Dong, Wen-Wen; Li, Dong-Sheng^*; Zhao, Jun; Wu, Ya-Pan; Wang, Yao-Yu

来源：Inorganic Chemistry Communications, 2012, 21: 53-56.

DOI：10.1016/j.inoche.2012.04.009

• 1,2,4-triazole
• Multi(bidentate)-ligand
• Cadmium compound
• Thermal stablilty
• Luminescent property

The first transition-metal coordination polymer {[Cd2L2(H2O)(2)]center dot 2H(2)O}(n) (1) based on a new 1,2,4-triazole derivatives H2L (H2L = 3-(pyrid-2-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazole) is presented, which not only exhibits an example assembled from 1D [Cd1L] chains to 3D (3,4)-connected network linked through [Cd2(trz)](2) dimeric units, but also shows high thermal stability and strong photoluminescence at room temperature.

• 出版日期2012-7
• 单位西北大学; 三峡大学