Access to catenated and branched polyphosphorus ligands and coordination complexes via a tri(pyrazolyl)phosphane

作者：Feldmann Kai Oliver; Froehlich Roland; Weigand Jan J^*

来源：Chemical Communications, 2012, 48(36): 4296-4298.

DOI：10.1039/c2cc18030h

We report a convenient and smooth protocol for the high-yielding synthesis of a triphosphane and an iso-tetraphosphane from a readily accessible tri(pyrazolyl)phosphane. The products are obtained from a one-pot reaction at room temperature and form complexes with the Fe(CO)(4)-fragment.

• 出版日期2012