An 18+delta iridium dimer releasing metalloradicals spontaneously

作者：Chen Tsun Ren^*; Lee Hsiu Pen; Chen Jhy Der; Chen Kelvin H C

来源：Dalton Transactions, 2010, 39(40): 9458-9461.

DOI：10.1039/c0dt00605j

Reductive elimination of a bridged chlorine from a diiridium(III) core, [(dfpbo)(2)Ir(mu-Cl)](2) (dfpbo = 2-(3.5-difluorophenyl) benzoxazolato-N,C(2)), afforded an iridium dimer, [(fpbo)(2)Ir](2)(mu-Cl), showing an 18+delta structure with a bent bridge, which can release metalloradicals spontaneously in solution at room temperature.

• 出版日期2010