摘要

Inorganic copper(I)/silver(I) halide/pseudohalide components are used to thread classical organic tetracationic macrocycles, cyclobis(paraquat-p-phenylene) and cyclobis(paraquat-4,4'-biphenylene), to construct crystalline inorganic organic adducts, featuring an unprecedented hybrid polyrotaxane and several unusual hybrid pseudorotaxanes and sandwiches.