A single Eu2+-activated high-color-rendering oxychloride white-light phosphor for white-light-emitting diodes

作者：Dai, Peng-Peng; Li, Cong; Zhang, Xin-Tong^*; Xu, Jun; Chen, Xi; Wang, Xiu-Li; Jia, Yan; Wang, Xiaojun^*; Liu, Yi-Chun

来源：Light: Science and Applications , 2016, 5(2): e16024.

DOI：10.1038/lsa.2016.24

• high-color-rendering
• single Eu2+-activated
• solid solution
• white-emitting phosphor

Single-phased, high-color-rendering index (CRI) white-light phosphors are emerging as potential phosphor-converted white-light-emitting diodes (WLEDs) and as an alternative to blends of tricolor phosphors. However, it is a challenge to create a high CRI white light from a single-doped activator. Here, we present a high CRI (Ra =91) white-light phosphor, Sr-5(PO4)(3-x)(BO3)(x)Cl:Eu2+, composed of Sr-5(PO4)(3)Cl as the beginning member and Sr-5(BO3)(3)Cl as the end member. This work utilized the solid-solution method, and tunable Eu2+ emission was achieved. Color-tunable Eu2+ emissions in response to structural variation were observed in Sr-5(PO4)(3-x)(BO3)(x)Cl solid solutions. This was further confirmed using X-ray Rietveld refinement, electron paramagnetic resonance spectroscopy, and in the photoluminescence spectra. The color-tunable emissions included the white light that originated from the combination of the blue emission of Sr-5(PO4)(3)Cl:Eu2+ and an induced Eu2+ yellow emission at approximately 550 nm in the solid solution. Importantly, the white-light phosphors showed a greater R9 = 90.2 under excitation at 365 nm. This result has rarely been reported in the literature and is greater than that of (R9 = 14.3) commercial Y3Al5O12:Ce3+-based WLEDs. These findings demonstrate the great potential of Sr-5(PO4)(3-x)(BO3)(x)Cl:0.04Eu(2+) as a white-light phosphor for near-UV phosphor-converted WLEDs. These results also provide a shortcut for developing a high CRI white-light phosphor from a single Eu2+-doped compound.

• 出版日期2016-2
• 单位东北师范大学