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摘要
Three catalyst samples 10wt% CuO/gamma-Al2O3 (CuAl), 10wt% CuO + 10wt% Cr2O3/gamma-Al2O3 (CuCrAl) and 10wt% CuO + 20wt% CeO2/gamma-Al2O3 (CuCeAl) have been taken for the study. Physico-chemical characteristics of the catalysts were determined by the methods of BET adsorption, X-ray diffraction and temperature-programmed reduction. Due to a strong interaction of CuO with Al2O3, resulting in the formation of copper aluminate the catalytic activity of CuO/gamma-Al2O3 has been reduced. The bi-oxide catalyst CuCrAl was more active than CuAl, thanks to the formation of high catalytically active spinel CuCr2O4. The fact of very high activity of the CuCeAl sample can be explained by the presence of the catalytically active form CuO-CeO2-Al2O3. The kinetics of CO oxidation reaction on the given catalysts was studied at the temperature range between 200 degrees C and 270 degrees C. The values of initial partial pressures of carbon monoxide (P-CO(o)), oxygen (P-O2(o)) and carbon dioxide (P-CO2(o)) were varied in ranges (hPa): 10 divided by 45; 33 divided by 100 and 0 divided by 30, respectively. It has been found that on all the catalysts, the common kinetic equation for the reaction was as follows:
r = kP(CO)P(O2)(0.5)/(1 + k(2)P(O2)(0.5) + k(3)P(CO2)),
where r is the reaction rate, k is the reaction constant, and k(2) and k(3) are the O-2 and CO2 adsorption constants, respectively. In the case of CuAl and CuCrAl, k(3) = 0, and since k(2)P(o2)(0.5) >> 1, the equation should become r = k.P-CO.
- 出版日期2011
