Nanosponge Formation from Organocatalytically Synthesized Poly(carbonate) Copolymers

作者:Stevens David M; Tempelaar Sarah; Dove Andrew P*; Harth Eva
来源:ACS Macro Letters, 2012, 1(7): 915-918.
DOI:10.1021/mz300179r

摘要

Advanced organocatalytic synthesis methods were employed to prepare linear poly(carbonate)s with control over functional group incorporation and molecular weight. Pendant allyl or epoxide groups served as reaction partners in thiol-ene click or epoxide-amine reactions with ethylene oxide-containing cross-linking groups to form a panel of six novel poly(carbonate) nanosponges with cross-linking densities ranging from 5, 10, and 20% via an intermolecular chain crosslinking approach.

  • 出版日期2012-7