Ag2O-Bi2O3 composites: synthesis, characterization and high efficient photocatalytic activities

作者:Zhu, Lin; Wei, Bo; Xu, Lingling*; Lu, Zhe; Zhang, Hailin; Gao, Hong; Che, Jixin
来源:CrystEngComm, 2012, 14(18): 5705-5709.
DOI:10.1039/c2ce25301a

摘要

Ag2O nanoparticle modified alpha-Bi2O3 composite photocatalysts were synthesized and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and UV-vis diffuse reflectance spectroscopy. XRD patterns confirmed that the composites consist of cubic phase Ag2O and monoclinic alpha-Bi2O3 phase. The Ag2O loading was greatly increased due to the rough surface of the acid etched Bi2O3 microrods. Photocatalytic activity of the Ag2O-Bi2O3 composites was evaluated using the degradation of methyl orange (MO). The correlation between the Ag2O content and photocatalytic activity was estimated. The composite with Ag to Bi ratio of 3 : 1 as raw material showed the highest visible light activity and the enhancement mechanism was attributed to the separation