AlB3O6(OH)center dot 0.5(C2H10N2): An organically templated aluminoborate with hnb-layer structure

作者：Liu Guang Zhen; Xin Ling Yun; Wang Li Ya^*

来源：Inorganic Chemistry Communications, 2011, 14(5): 775-777.

DOI：10.1016/j.inoche.2011.03.010

• Aluminoborate
• Hydrothermal synthesis
• Organic template
• Layered structure

A novel organically templated aluminoborate, AlB3O6(OH)center dot 0.5(C2H10N2) 1 was synthesized under hydrothermal conditions and structurally characterized by single crystal X-ray diffraction. Its aluminoborate architecture features the alternative connection of AlO3(OH) tetrahedra and B3O6 polyanions, giving rise to a sheet with hnb topology. Two adjacent antiparallel sheets sandwich H(2)en templates by hydrogen bonding interactions to produce a slab block (en = ethylenediamine). These slab blocks are stacked in a -AAAA-sequence and further cohered entirely by relatively weak van der Waals interactions to form its entire structure. Further characterizations for 1 are accomplished by IR, element analysis, and thermal analysis.

• 出版日期2011-5
• 单位洛阳师范学院