Gold(I)-Catalyzed Synthesis of gamma-Hydroxyketones from 5-Allyloxy-1-ynes

作者:Cheong Jae Youp; Im Donghong; Lee Miryeong; Lim Wontaeck; Rhee Young Ho*
来源:Journal of Organic Chemistry, 2011, 76(1): 324-327.
DOI:10.1021/jo102005x

摘要

The Au(I)-catalyzed reactions of 5-allyloxy-1-ynes gave various gamma-hydroxyketones, via a hydration-terminated domino sequence involving sigmatropic allyl migration as the key event. Moreover, the scope of the sigmatropic allyl transfer was systematically determined.

  • 出版日期2011-1-7