A water reduction process performed by zinc metal under very mild conditions

作者:Romero Maria J; Pedrido Rosa*; Gonzalez Noya Ana M; Martinez Calvo Miguel; Zaragoza Guillermo; Bermejo Manuel R
来源:Chemical Communications, 2010, 46(28): 5115-5117.
DOI:10.1039/c0cc00256a

摘要

Water reduction can be electrochemically promoted by zinc under very mild conditions, as demonstrated by the formation of the complex [Zn(H(2)O)(6)][Zn(3)(L)(3)(mu(3)-O)], whose anion consists of a Zn(3)O(4) cluster incorporating a mu(3)-oxo anion.

  • 出版日期2010