A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds

作者:Lar Claudia; Woiczechowski Pop Adrian; Bende Attila; Grosu Ioana Georgeta*; Miklasova Natalia; Bogdan Elena; Hadade Niculina Daniela; Terec Anamaria*; Grosu Ion*
来源:Beilstein Journal of Organic Chemistry, 2018, 14: 1370-1377.
DOI:10.3762/bjoc.14.115

摘要

The aromatic nucleophilic substitution reaction based synthesis of a three-armed cryptand displaying 2,4,6-triphenyl-1,3,5-triazine units as caps and pyridine rings in the bridges, along with NMR, MS and molecular modelling-based structural analysis of this compound are reported. Appropriate NMR and molecular modelling investigations proved the formation of 1:1 host-guest assemblies between the investigated cryptand and some polynuclear aromatic hydrocarbons or their derivatives.

  • 出版日期2018-6-6