Layered double hydroxides/polymer thin films grown by matrix assisted pulsed laser evaporation

作者：Birjega R^*; Matei A; Mitu B; Ionita M D; Filipescu M; Stokker Cheregi F; Luculescu C; Dinescu M; Zavoianu R; Pavel O D; Corobea M C

来源：Thin Solid Films, 2013, 543: 63-68.

DOI：10.1016/j.tsf.2013.02.120

• Double layered hydroxides
• Thin films
• MAPLE
• Composites

Due to their highly tunable properties, layered double hydroxides (LDHs) are an emerging class of the favorably layered crystals used for the preparation of multifunctional polymer/layered crystal nanocomposites. In contrast to cationic clay materials with negatively charge layers, LDHs are the only host lattices with positively charged layers (brucite-like), with interlayer exchangeable anions and intercalated water. %26lt;br%26gt;In this work, the deposition of thin films of Mg and Al based LDH/polymers nanocomposites by laser techniques is reported. Matrix assisted pulsed laser evaporation was the method used for thin films deposition. The Mg-Al LDHs capability to act as a host for polymers and to produce hybrid LDH/polymer films has been investigated. Polyethylene glycol with different molecular mass compositions and ethylene glycol were used as polymers. The structure and surface morphology of the deposited LDH/polymers films were examined by X-ray diffraction, Fourier transform infra-red spectroscopy, atomic force microscopy and scanning electron microscopy.

• 出版日期2013-9-30