An Acid-stable Organoruthenium Complex Suitable as a Bidentate Building Block

作者：Zheng Chunbai; Inoki Daisuke; Matsumoto Takahiro; Ogo Seiji^*

来源：Chemistry Letters, 2010, 39(2): 130-131.

DOI：10.1246/cl.2010.130

A new, water-soluble organoruthenium(II) sulfato Complex [Ru-II(SO4)(Bz boolean AND py)] {1, Bz boolean AND py = 2-(pentamethylbenzyl)pyridine} has been synthesized and is stable at pH from 2.0 to 8.0. This complex has a bidentate sulfato ligand as a leaving group arid is a good building block for "concerto catalysis": a new way of thinking in catalysis that bridges hetero- and homogeneous catalysis.

• 出版日期2010-2-5