High Activity Oxygen Evolution Reaction Catalysts from Additive-Controlled Electrodeposited Ni and NiFe Films

作者：Hoang Thao T H; Gewirth Andrew A^*

来源：ACS Catalysis, 2016, 6(2): 1159-1164.

DOI：10.1021/acscatal.5b02365

• water splitting
• electrocatalyst
• oxygen evolution
• electrodeposition
• NiFe

Electrodeposition of Ni or NiFe films exhibiting fractal-like behavior from plating baths containing an inhibitor, such as 3,5-diamino-1,2,4-triazole (DAT), is found to yield oxygen evolution reaction (OER) catalysts for alkaline solutions exhibiting high current densities (100 mA/cm(2)), high mass activity (similar to 1200 A/g of catalyst), high stability (>72 h), and low overpotentials (similar to 300 mV). By changing electrodeposition time, the activity of the catalyst can be tuned, with longer times yielding higher activities. The electrodeposition method works with any conductive substrate yielding unprecedented performance and providing an easy route to high activity catalysts.

• 出版日期2016-2