Microwave-assisted synthesis of graphene/CoMoO4 nanocomposites with enhanced supercapacitor performance

作者：Xu Xiaowei; Shen Jianfeng; Li Na; Ye Mingxin^*

来源：Journal of Alloys and Compounds, 2014, 616: 58-65.

DOI：10.1016/j.jallcom.2014.07.047

• Supercapacitor
• Cobalt molybdate
• Graphene
• Microwave
• Nanocomposite

A facile and efficient strategy for preparing reduced graphene oxide-cobalt molybdate (RGO/CoMoO4) nanocomposites assisted by microwave irradiation for the first time is demonstrated. The resulting nanocomposites are comprised of CoMoO4 nanoparticles that are well-anchored on graphene sheets by in situ reducing. The prepared RGO/CoMoO4 nanocomposites have been thoroughly characterized by Fourier-transform infrared spectroscopy, X-ray diffraction, Raman spectroscopy, thermogravimetric analysis, scanning electron microscopy and X-ray photoelectron spectroscopy. Importantly, the prepared nanocomposites exhibit excellent electrochemical performance for supercapacitors. Results show that RGO/CoMoO4 nanocomposites exhibited much better electrochemical capability than pure-CoMoO4 and RGO/CoMoO4 for annealing. RGO/CoMoO4 nanocomposites with 37.4 wt% CoMoO4 content achieved a specific capacitance about 322.5 F g(-1) calculated from the CV plots at 5 mV s(-1), which was higher than that of pure-CoMoO4 (95.0 F g(-1)) and RGO/CoMoO4 for annealing (102.5 F g(-1)). The good electrochemical performance can be attributed to the synergistic effects of the individual components.

• 出版日期2014-12-15
• 单位复旦大学