A Two-Fold Interpenetrating Ni(II) Coordination Polymer Based on 1,2-Bis(imidazol-1-ylmethyl)benzene and 4,4'-Oxybis(benzoate)

作者：Kong Zhi Guo^*; Lu Ting Feng; Wang Qing Wei

来源：Chinese Journal of Inorganic Chemistry, 2011, 27(11): 2271-2274.

• coordination polymer
• crystal structure
• 4,4'-oxybis(benzoate)
• 1,2-bis(imidazol-1-ylmethyl)benzene

A coordination polymer, [Ni(2)(1,2-bix)(2)(oba)(2)(H(2)O)(2)] (1) (1,2-bix=1,2-bis(imidazol-1-ylmethyl)benzene and oba=4,4' -oxybis (benzoate)), has been hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Crystal data: C(56)H(48)N(8)Ni(2)O(12), monoclinic, space group P2(1)/n, a= 1.475 3(5) nm, 6=1.684 1(4) nm, c=2.135 6(5) nm, beta=102.864(3)degrees, V=5.173(2) nm(3), Z=4, R=0.040 5, wR=0.101 0. In complex 1, the central Ni (II) atoms are bridged by the 1,2-bix ligands and oba anions to form a two-dimensional (2D) (4,4) network. Two 2D (4,4) networks interpenetrated in a two-fold mode. In addition, the O-H ...O hydrogen-bonding interactions further stabilize the network structure of complex 1. CCDC: 818375.

• 出版日期2011-11-10
• 单位吉林师范大学