A New Class of Ionic Liquids: Anion Amphiprotic Ionic Liquids

作者：Treskow Marcel; Pitawala Jagath; Arenz Sven; Matic Aleksandar; Johansson Patrik^*

来源：Journal of Physical Chemistry Letters, 2012, 3(16): 2114-2119.

DOI：10.1021/jz300752u

We here present a new class of protic ionic liquids, anion amphiprotic ionic liquids (AAILs). These materials are protonation equilibrium free protic ionic liquids and interesting in their own right by not following the classical Bronsted acid-base neutralization concept Due to the very simple synthesis route applied and their stable basic chemistry, we believe in a potential use for manifold applications. This is supported by the combination of practical material properties, foremost, a general intrinsic stability versus reversal of the formation reaction toward neutral species, broad liquidus ranges, long-term thermal stabilities, high conductivities, protic characteristics, and a general stability versus water.

• 出版日期2012-8-16