Allyl sulphides in olefin metathesis: catalyst considerations and traceless promotion of ring-closing metathesis

作者:Edwards Grant A; Culp Phillip A; Chalker Justin M*
来源:Chemical Communications, 2015, 51(3): 515-518.
DOI:10.1039/c4cc07932a

摘要

Allyl sulphides are reactive substrates in ruthenium-catalysed olefin metathesis reactions, provided each substrate is matched with a suitable catalyst. A profile of catalyst activity is described, along with the first demonstration of allyl sulphides as traceless promoters in relayed ring-closing metathesis reactions.

  • 出版日期2015