Dithieno[2,3-d:2%26apos;,3%26apos;-d%26apos;]benzo[1,2-b:4,5-b%26apos;]dithiophene (DTBDAT)-based copolymers for high-performance organic solar cells

作者：Lee Ye Seul; Song Seyeong; Yoon Yung Jin; Lee Yun Ji; Kwon Soon Ki; Kim Jin Young; Kim Yun Hi

来源：Journal of Polymer Science Part A: Polymer Chemistry , 2016, 54(19): 3182-3192.

DOI：10.1002/pola.28205

• conjugated polymers
• synthesis
• structure-property relations

P(BDT-TCNT) and P(DTBDAT-TCNT), which has an extended conjugation length, were designed and synthesized for applications in organic solar cell (OSCs). The solution absorption maxima of P(DTBDAT-TCNT) with the extended conjugation were red-shifted by 5-15 nm compared with those of P(BDT-TCNT). The optical band gaps and highest occupied molecular orbital (HOMO) energy levels of both P(BDT-TCNT) and P(DTBDAT-TCNT) were similar. The structure properties of thin films of these materials were characterized using grazing-incidence wide-angle X-ray scattering and tapping-mode atomic force microscopy, and charge carrier mobilities were characterized using the space-charge limited current method. OSCs were formed using [6,6]-phenyl-C-71-butyric acid methyl ester (PC71BM) as the electron acceptor and 3% diphenylether as additive suppress aggregation. OSCs with P(BDT-TCNT) as the electron donor exhibited a power conversion efficiency (PCE) of 4.10% with a short-circuit current density of J(SC)=9.06 mA/cm(2), an open-circuit voltage of V-OC=0.77 V, and a fill factor of FF=0.58. OSCs formed using P(DTBDAT-TCNT) as the electron donor layer exhibited a PCE of 5.83% with J(SC)=12.2 mA/cm(2), V-OC=0.77 V, and FF=0.62.

• 出版日期2016-10-1