Determination and Correlation of Solubilities of Lithium Bis(oxalate)borate in Six Different Solvents from (293.15 to 363.15) K

作者：Chen Fuchun; Hu Jinhuo; Chen Zhengyu; Yang Zhenyu^*; Gu Ningyu

来源：Journal of Chemical and Engineering Data, 2014, 59(5): 1614-1618.

DOI：10.1021/je500068b

The solubility data of lithium bis(oxalate)borate (LiBOB) were measured in six different solvents using the synthetic method and laser monitoring technique at temperatures ranging from (293.15 to 363.15) K under atmospheric pressure. The experimental solubilities of LiBOB in different solvents were correlated by the modified Apelblat equations. It is found the calculated solubility data show good consistency with the experimental values. On this basis, some thermodynamic parameters of LiBOB in different solvents, such as dissolution enthalpy, dissolution entropy, and dissolution Gibbs free energy, are also calculated. These results concerning the solubility of LiBOB in different solvents will provide fundamental data in the commercial application of LiBOB.

• 出版日期2014-5
• 单位南昌大学