Aqua(3,5-dinitrosalicylato-kappa O)bis(1,10-phenanthroline-KAPPA N,N ')manganese(II)3,5-dinitrosalicylate

作者：Song, Wen-Dong^*; Yan, Jian-Bin; Guo, Xian-Xia; Ng, Seik Weng

来源：Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M1307-M1308.

DOI：10.1107/S160053680701714X

• single-crystal X-ray study
• T=293 K
• mean sigma(C
• C)=0.005 angstrom
• disorder in main residue
• R factor=0.047
• wR factor=0.143
• data-to-parameter ratio=14.9

In the title compound, [Mn(C7H3N2O7)(C12H8N2)(2)(H2O)]-(C7H2N2O7), the Mn-II ion is chelated by two phenanthroline ligands, a water molecule and a carboxylate group in an octahedral geometry; the two O atoms involved in bonding are cis to each other. The coordinated water molecule links the cation and the carboxylate anion into a linear chain through hydrogen bonds.

• 出版日期2007-5
• 单位广东海洋大学