Lanthanoid(II) tetraphenylborate complexes: From discrete ions to pseudo metallocenes

作者：Deacon Glen B; Evans David J; Forsyth Craig M; Junk Peter C^*

来源：Coordination Chemistry Reviews, 2007, 251(13-14): 1699-1706.

DOI：10.1016/j.ccr.2006.11.005

• lanthanoids
• lanthanoid(II)
• tetraphenylborate
• weakly coordinating anions
• rare earths

This article describes the synthetic strategies, structural features and reactivity of a unique class of discrete cationic lanthanoid(II) complexes with tetraphenylborate counter ions. In addition, variable binding of these 'weakly coordinating anions' (WCA) to the large electropositive f-element metal cations can also occur.

• 出版日期2007-7