A reliable amplified fluorescence-enhanced chemosensor (Eu-MIL-61) for the directional detection of Ag+ in an aqueous solution

作者：Sun, Nana; Yan, Bing^*

来源：Dalton Transactions, 2017, 46(3): 875-881.

DOI：10.1039/c6dt04335f

• METAL-ORGANIC FRAMEWORK
• LEWIS BASIC SITES
• COORDINATION POLYMERS
• SILVER IONS
• LUMINESCENT PROPERTIES
• ESCHERICHIA-COLI
• STORAGE CAPACITY
• MOF
• SENSOR
• ADSORPTION

A robust gallium carboxylate Ga(OH)(btec) U 0.5H(2)O (MIL-61) was synthesized under mild hydrothermal conditions and selected as the parent MOF to prepare Eu-MIL-61 by post-synthetic modification due to the uncoordinated carbonyl group of the ligand (pyromellitic acid (H4btec)). The firm framework, permanent porosity, and non-coordinated sites make MIL-61 a good scaffold for immobilizing and sensitizing Eu3+. The products showed excellent luminescence and, more significantly, Eu-MIL-61 showed excellent selectivity with photoluminescence enhancement, fast response time, and low detection limit for Ag+ ions in the aqueous solutions. In addition, the frameworks were not susceptible to the acid-base property of solutions, which can be further applied to monitor the concentration of Ag+ in several daily water samples.

• 出版日期2017-1-21
• 单位同济大学