UV-assisted room-temperature chemiresistive NO2 sensor based on TiO2 thin film

作者:Xie Ting*; Sullivan Nichole; Steffens Kristen; Wen Baomei; Liu Guannan; Debnath Ratan; Davydov Albert; Gomez Romel; Motayed Abhishek
来源:Journal of Alloys and Compounds, 2015, 653: 255-259.
DOI:10.1016/j.jallcom.2015.09.021

摘要

TiO2 thin film based, chemiresistive sensors for NO2 gas which operate at room temperature under ultraviolet (UV) illumination have been demonstrated in this work. The rf-sputter deposited and post-annealed TiO2 thin films have been characterized by atomic force microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction to obtain surface morphology, chemical state, and crystal structure, respectively. UV-vis absorption spectroscopy and Tauc plots show the optical properties of the TiO2 films. Under UV illumination, the NO2 sensing performance of the TiO2 films shows a reversible change in resistance at room-temperature. The observed change in electrical resistivity can be explained by the modulation of surface-adsorbed oxygen. This work is the first demonstration of a facile TiO2 sensor for NO2 analyte that operates at room-temperature under UV illumination.

  • 出版日期2015-12-25