Adsorption of carbon dioxide and nitrogen on zeolite rho prepared by hydrothermal synthesis using 18-crown-6 ether

作者：Araki Sadao^*; Kiyohara Yasato; Tanaka Shunsuke; Miyake Yoshikazu

来源：Journal of Colloid and Interface Science, 2012, 388: 185-190.

DOI：10.1016/j.jcis.2012.06.061

• Zeolite rho
• Carbon dioxide
• Adsorbent
• 18-Crown-6

Zeolite rho was prepared by hydrothermal synthesis using an 18-crown-6 ether (18C6) as a structure-directing agent, and the effects of the calcination temperature for removal of 18C6 on the physicochemical properties and CO2-adsorption properties were investigated. CO2 adsorption on zeolite rho calcined at 150 degrees C was lower than that on samples calcined at temperatures above 300 degrees C. For samples calcined above 300 degrees C, CO2 adsorption increased with increasing calcination temperature up to 400 degrees C. It is thought that the pore volume for adsorption of CO2 increased as a result of 18C6 removal, resulting in increasing CO2 adsorption. A decrease in CO2 adsorption for calcination from 400 degrees C to 500 degrees C was observed. The particle size of zeolite rho increased with increasing 18C6 molar ratio. Particle sizes of 1.0-2.1 mu m and 1.4-2.6 mu m were found by field-emission scanning electron microscopy and dynamic light-scattering, respectively. The particle size is controlled in these regions by adjusting the 18C6 molar ratio. XRD showed that zeolite rho samples with 18C6 molar ratios of 0.25-1.5 had high crystallinity. The adsorbed amount of CO2 is almost constant, at 3.4 mmol-CO2 g(-1), regardless of the 18C6 molar ratio. However, CO2 selectivity, which is the CO2/N-2 adsorption ratio, decreased. The amount of CO2 adsorbed on zeolite rho is lower than that on zeolite NaX, but higher than that on SAPO-34. The CO2/N-2 adsorption ratio for zeolite rho was higher than those for SAPO-34 and zeolite NaX.

• 出版日期2012-12-15