Diastereoselective Synthesis of Planar Chiral Phosphoramidites with a Ferrocenophane Scaffold

作者：Neel Mathilde; Retailleau Pascal; Voituriez Arnaud; Marinetti Angela

来源：Organometallics, 2018, 37(5): 797-801.

DOI：10.1021/acs.organomet.7b00700

A new family of planar chiral phosphoramidites with a [3]ferrocenophane structure was synthesized. The synthetic strategy involved diastereoselective formation of the chiral ferrocene units from suitable substituted bis-cyclopentadienyl derivatives. Preliminary coordination studies of these ligands were undertaken with the synthesis of palladium and platinum complexes.

• 出版日期2018-3-12