A New 3-D Mn(II) Naphthoic Acid Complex [Mn(1,4-DNC)(DMA)](n) (1,4-DNC=1,4-Naphthalenedicarboxylate, DMA = Dimethylacetamide)

作者：Lu, Ying-Bing^*; Jin, Shuang; Jian, Fang-Mei; Xie, Yong-Rong; Luo, Guo-Tian

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2016, 46(3): 323-326.

DOI：10.1080/15533174.2014.988232

• coordination
• manganese(II)
• 1,4-naphthalenedicarboxylate
• 3-D

A new 3-D Mn(II)-organic extended framework with a 1,4-naphthalenedicarboxylate ligand, [Mn(1,4-DNC)(DMA)](n) (1), was obtained by the solvothermal reaction of MnCl(2)4H(2)O and 1,4-naphthalenedicarboxylate (1,4-H2DNC) in dimethylacetamide organic solvents. Each Mn(II) atom is five-coordinated in a triagonal-bipyramidal coordination environment by four carboxylate O atoms from four different 1,4-DNC2- ligands and one O atom from a terminal DMA molecule. The neighboring Mn(II) atoms are doubly bridged by 1,4-DNC2- ligands to give a one-dimensional coordination polymeric chain [Mn(COO)(2)](n), and each chain is connected to four other different chains through mu(4)-kO1: kO2: kO3: kO4 1,4-DNC2- ligands to form a 3-D network of 1.

• 出版日期2016-3-3
• 单位赣南师范大学