Alkali metal complexes of tridentate amine-bis(phenolate) ligands and their rac-lactide ROP activity

作者：Saunders Lisa N; Dawe Louise N; Kozak Christopher M^*

来源：Journal of Organometallic Chemistry, 2014, 749: 34-40.

DOI：10.1016/j.jorganchem.2013.09.012

• Alkali metals
• Lactide
• Ring opening polymerization
• N,O-ligands

Three complexes were prepared using lithium, sodium and potassium reagents and an amine-(bis) phenol proligand. The proligand, benzylamino-N,N-bis(2-methylene-4-methyl-6-tert-butylphenol) (abbreviated H-2[L]), was reacted with n-butyllithium to give the lithium complex, Li-2[L] (1), and NaH or KH to give the sodium, Na-2[L] (2), and potassium, K-2[L] (3), complexes, respectively. The compounds were also found to contain varying numbers of coordinated THF molecules. These complexes were characterized using H-1, C-13, and Li-7 NMR (for the lithium complex), MALDI-TOF MS, elemental analysis and FT-IR. The potassium complex (3) was characterized in the solid state and exhibits eta(6) K-arene bonds as well as eta(1)-bonding of the K ion to the ipso-carbons of the phenolate fragments. The reactivity of 1-3 towards the ring-opening polymerization of rac-lactide to form polylactide (PLA) was explored.

• 出版日期2014-1-1