Nonheme ferric hydroperoxo intermediates are efficient oxidants of bromide oxidation

作者：Vardhaman Anil Kumar; Sastri Chivukula V^*; Kumar Devesh; de Visser Sam P

来源：Chemical communications, 2011, 47(39): 11044-11046.

DOI：10.1039/c1cc13775a

This work presents the first combined experimental and computational study that gives evidence of the electrophilic reactivity of a nonheme iron(III)-hydroperoxo species. We show that in contrast to their heme counterparts the nonheme iron(III)-hydroperoxo complexes are catalytically much more active and even more so than nonheme iron(IV)-oxo species.

• 出版日期2011