A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors

作者：Prochowicz D; Sokolowski K; Justyniak I; Kornowicz A; Fairen Jimenez D; Friscic T; Lewinski J^*

来源：Chemical communications, 2015, 51(19): 4032-4035.

DOI：10.1039/c4cc09917f

We demonstrate a mechanochemical strategy that allowed the first successful mechanosynthesis of IRMOFs based on an oxo-centred secondary building unit (SBU). The presented study indicates that controlling the acid-base relationship between reagents is key to mechanochemical synthesis of IRMOFs, revealing a pre-assembled oxo-zinc amidate cluster as an efficient precursor for IRMOF mechanosynthesis.

• 出版日期2015