Attempted synthesis of 2-oxo-N-phenyltetracyclo[7.2.1.0(2,6).0(5,11)]-dodecane-9,10-dicarboximi de by intramolecular alpha-ketocarbene insertion into an unactivated C-H bond

作者：Camps Pelayo^*; Fernandez Jose A; Vazquez Santiago; Font Bardia Merce; Solans Xavier

来源：ARKIVOC, 2011, 358-368.

• 9-Borabicyclo[3.3.1]nonane
• diastereoselective hydroboration
• alpha-diazoketone
• attempted intramolecular alpha-ketocarbene C-H insertion

The diastereoselective preparation of 4 alpha-(diazomethylcarbonyl)-N-phenyltricyclo[5.2.1.0(2,6)]-decane- 2 beta,6 beta-dicarboximide and attempts to transform this compound into a derivative containing the tetracyclo[7.2.1.0(2,6).0(5,11)]dodecane skeleton are described.

• 出版日期2011