Gold(I)-Catalyzed Inter- and Intramolecular Additions of Carbonyl Compounds to Allenenes

作者：Jimenez Tania; Carreras Javier; Ceccon Julien; Echavarren Antonio M^*

来源：Organic Letters, 2016, 18(6): 1410-1413.

DOI：10.1021/acs.orglett.6b00342

The gold(I)-catalyzed intramolecular reaction of allenes with oxoalkenes leads to bicyclo[6.3.0]undecane ring systems, although in the case of terminally disubstituted allenes, seven-membered rings are formed. The related intermolecular addition of aldehydes to allenenes also gives seven-membered rings.

• 出版日期2016-3-18