Acid- and base-functionalized core-confined bottlebrush copolymer catalysts for one-pot cascade reactions

作者：Xiong, Linfeng; Zhang, Hui; Zhong, Aiqing; He, Zidong; Huang, Kun^*

来源：Chemical Communications, 2014, 50(94): 14778-14781.

DOI：10.1039/c4cc06573e

We demonstrate a novel method that enables the formation of core-confined bottlebrush copolymers (CCBCs) as catalyst supports. Significantly, owing to the site-isolated effect, these CCBC catalysts with the incompatible acidic para-toluenesulfonic acid (PTSA) and basic 4-(dimethylamino)pyridine (DMAP) groups can conduct a simple two-step sequential reaction in one vessel.

• 出版日期2014
• 单位华东师范大学