A Luminescent Cage-Like Complex Constructed by Bidentate Pyridine-Containing Ligand and Silver Nitrate

作者：Liu Ying; Yu Ying Hui; Liu Yi Fu; Hou Guang Feng; Wang Xiao Dan; Wen Bo; Gao Jin Sheng^*

来源：Zeitschrift fur Anorganische und Allgemeine Chemie, 2013, 639(1): 193-196.

DOI：10.1002/zaac.201200344

• Cage-like complexes
• Flexible bidentate ligand
• Silver
• Crystal structure

The cage-like complex, Ag4L4(NO3)4 (1) [L = 1, 4-bis(pyridine-2-ylmethoxy)benzene] was synthesized by the reaction of the flexible bidentate ligand and silver nitrate. It was characterized by elemental analysis, IR spectroscopy, TG, and single-crystal X-ray analysis. Complex 1 is reported as the first cage-like cluster constructed by four nitrate anions bridging two [2+2] macrocycles. A blue luminescent emission and luminescent enhancement effect are observed in complex 1.

• 出版日期2013-1
• 单位黑龙江大学; 黑龙江工程学院