mu-1,4-bis(diphenylphosphino)butane-kappa P-2 : P '-bis[2,2 '-bipyridyl)silver(I)]ditetrafluoroborate

作者:Zhang, L; Chen, CL; Zhang, Q; Zhang, HX; Kang, BS*
来源:Acta Crystallographica Section E-Structure Reports Online, 2003, 59: M536-M537.
DOI:10.1107/S1600536803013813

摘要

Pink crystals of the title dinuclear complex, [Ag-2(C10H8N2)(2)(C28H28P2)](BF4)(2), were obtained from a methanol solution of equivalent amounts of AgBF4, 2,2'-bipyridyl (bipy) and 1,4- bis(diphenylphosphino) butane (dppb). The [Ag-2(bipy)(2)(dppb)](2 ) cation lies across a crystallographic inversion centre and the coordination environment around Ag-I is distorted trigonal.