Manipulation and measurement of pH sensitive metal-ligand binding using electrochemical proton generation and metal detection

作者：Read Tania L; Joseph Maxim B; Macpherson Julie V

来源：Chemical Communications, 2016, 52(9): 1863-1866.

DOI：10.1039/c5cc09326k

Generator-detector electrodes can be used to both perturb and monitor pH dependant metal-ligand binding equilibria, in situ. In particular, protons generated at the generator locally influence the speciation of metal (Cu2+) in the presence of ligand (triethylenetetraamine), with the detector employed to monitor, in real time, free metal (Cu2+) concentrations.

• 出版日期2016