An in Situ Embedded Square-Planar Cu-II/(NiN4)-N-II Metalloligand in Coordination Polymers for Visible-Light Photocatalysis

作者：Hou, Yun-Long; Pi, Yunhong; Zhou, Xiao-Ping; Li, Dan^*

来源：Inorganic Chemistry, 2018, 57(5): 2377-2380.

DOI：10.1021/acs.inorgchem.7b03068

• METAL-ORGANIC FRAMEWORKS
• ENANTIOSELECTIVE CATALYST
• HYDROGEN-PEROXIDE
• COMPLEXES
• OXIDATION
• MOF
• DEGRADATION
• LUMINESCENT
• CHEMISTRY
• HALIDES

Three coordination polymers (CPs) with square-planar Cu-II/Ni-4(II) subunits were formed in one step by subcomponent self-assembly, giving rise to an unprecedented linking, variety of in situ embedded metalloligands and Cul clusters. All CPs exhibit unusual visible-light adsorption. Enhanced photocatalytic activity and high selectivity were observed in the oxidation of benzene under visible-light irradiation.

• 出版日期2018-3-5
• 单位香港城市大学; 汕头大学; 暨南大学