Ni-Cu and Ni-Co alloys: Synthesis, structure, and catalytic activity for the decomposition of chlorinated hydrocarbons

作者：Rudnev A V^*; Lysakova A S; Plyusnin P E; Bauman Yu I; Shubin Yu V; Mishakov I V; Vedyagin A A; Buyanov R A

来源：Inorganic Materials, 2014, 50(6): 566-571.

DOI：10.1134/S0020168514060156

Homogeneous Ni (x) Cu1 - x and Ni (x) Co1 - x (x = 0.90-0.99) alloys have been prepared through the coprecipitation of precursors (hydroxides or carbonates) and reduction of the precipitate. The formation of single-phase Ni (x) M1 - x alloys in all of the samples has been confirmed by X-ray diffraction. We have assessed the catalytic activity of the alloys for 1,2-dichloroethane decomposition with carbon nanomaterial (CNM) formation. The highest catalytic activity (CNM yield, 26-27 g/g(cat)) was offered by the nickel alloys containing similar to 1 at % Cu or Co. The carbon material obtained has the form of segmented submicron wires with high morphological uniformity.

• 出版日期2014-6