Ammonia induced formation of N-doped (BiO)(2)CO3 hierarchical microspheres: the effect of hydrothermal temperature on the morphology and photocatalytic activity

作者：Dong Fan^*; Xiong Ting; Zhao Zaiwang; Sun Yanjuan; Fu Min

来源：CrystEngComm, 2013, 15(48): 10522-10532.

DOI：10.1039/c3ce41634h

Three types of N-doped (BiO)(2)CO3 hierarchical microspheres composed of 2D nanosheets were fabricated by a one-pot template-free hydrothermal method from bismuth citrate and an ammonia solution under different hydrothermal temperatures. The as-prepared samples were characterized by X-ray diffraction, scanning electron microscopy, nitrogen adsorption-desorption isotherms, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy and UV-visible diffuse reflectance spectroscopy. Here, the ammonia worked as a nitrogen resource, doping (BiO)(2)CO3, and a solvent hydrolyzing the bismuth citrate. The temperature was found to influence the thickness of the nanosheets and the morphology of the N-doped (BiO)(2)CO3 microspheres. The fascinating morphology of N-doped (BiO)(2)CO3, including rose-like, hydrangea flower-like and peony flower-like microspheres, can be controllably fabricated by adjusting the hydrothermal temperature. The photocatalytic activities of the as-prepared samples were evaluated towards the removal of NO under visible-light irradiation. Compared to pure (BiO)(2)CO3, the N-doped (BiO)(2)CO3 hierarchical microspheres showed enhanced photocatalytic activity. In addition, the hydrangea flower-like and the peony flower-like N-doped (BiO)(2)CO3 microspheres displayed admirable photocatalytic activity. Finally, a possible formation mechanism of the various morphologies of N-doped (BiO)(2)CO3 mediated by the reaction temperature was proposed. This work could provide new insights into the controlled synthesis of photocatalytic nano/microstructures for potential environmental applications.

• 出版日期2013
• 单位中国环境监测总站; 重庆工商大学